I would say that Ron has knowledge about exhaust gas analysis, since he has a 5 gas analyser, I watched him use on a vehicle that went to Zero on both Hc and CO after the Groove, and put my face at the pipe tip-only hot moist air w/no smell!
One other thing that can be measured pre and post Groove is temps. Get a decent infrared thermometer I think even Harbor Freight has 'em now. you want one that can go to say at least 600 deg.F or higher since cat's get that hot. Once engine is warmed up after some driving take/record temps at: all cat's, exhaust manifolds, thermostat housing, anyplace that gets hot during operation where temp's could be affected by operating characteristics. Repeat After Grooving, PCV re-route, and computer re-learn procedure.
You could also get a white cloth and hold over exh. pipe tip for a measured legnth of time before/after watch for a change in soot. Might want to give some miles after Grooving to let things clean out.
Those are my ideas, sounds like yours runs well now and your cats are working well too. will you hit Zero Emissions...?
Good Luck Keep us Posted!
TracyG Gadgetman Reno