Hi Greg, glad to hear you cured the idle RPM issue! (thanks to Dr. Ron!)
For temps on cats-- clear a small area of foil off the cat's to shoot temps on. Foil will just reflect the laser off giving bad reading. Needs a dull dark surface to shoot. Crawl around under there till you find a good angle to shoot the temp gun on cats that you can repeat, clear a small patch an inch square or so. For under a load readings, find a stretch of road where ya can get load/rpm's up a ways then able to pull over quickly, where you can crawl down there Safely. We don't want ya gettin run over!!

Like plotting a road route for the computer re-learn.
I'm gonna guess that w/ new cat's & exhaust it ought not get TOO hot down there. Might research but think I rember that cat's need 5-600 deg.F to even light off. Old ones can clog from carbon junk and even melt inside and that's not good. I did fix a Ford truck once that had engine fire from plugged cat that warped the straight 6 exhaust manifold into an arch--but was because some fool put Leaded gas in it! w/a good clean running engine excess temps ought not to be an issue esp w/ new stuff like you have. But-i'd monitor those temps awhile w/ the wrap from under different driving cond. just to be sure.
And BTW, I don't remember--what kinda shape are plugs//wires cap/rotor in? Ever check/re-gap the plugs? My experience is those parts just get ignored 'till they are Real Bad causing prob's. not sayin' that's you, Greg, and I don't remember if ya talked 'bout that already!
I'm the resident Ignition Fanatic, 'cause I have found gains there, and good Ignition sets a good foundation for all else.
Cheers!
Tracy G